Battery knowledge · Other and emerging chemistries

Sodium–nickel chloride battery

A high-temperature cell, run at about 270–350 °C, with molten sodium as negative, nickel and nickel chloride in molten sodium tetrachloroaluminate as positive, and a β″-alumina ceramic electrolyte between them, giving 2.58 V. Failed cells fail to low resistance, so a series string keeps working; it has served in buses, telecom backup and grid storage.

Abbreviation
ZEBRA
Also called
Na–NiCl₂, molten-salt battery

Example

Other and emerging chemistries: an example situation

Two chemistries can meet the same energy target with different voltage windows and charge termination.

Read Sodium–nickel chloride battery alongside Electric bus in this context. A battery-electric city or coach bus, with packs of 300–700 kWh on the roof and at the rear, LFP or NMC, charged overnight in the depot or at the terminus by pantograph. Its duty cycle — long hours, deep daily cycles, a twelve-year life — makes battery aging the central engineering question.

Use in Lemonergy

Do not carry lithium-ion assumptions into every chemistry.

This is a reference concept. No executable Lemonergy block has been verified for this term.

References & further reading

Further reading on this topic

These sources provide broader context; they are not presented as citations for every statement in this entry.

  1. Promise and reality of post-lithium-ion batteries with high energy densities

    Jang Wook Choi, Doron Aurbach · Nature Reviews Materials · 2016

    Topic background · Post-lithium-ion materials and battery concepts, including practical cell-level limitations; historical 2016 perspective.

  2. DOE/EPRI 2013 Electricity Storage Handbook in Collaboration with NRECA

    Sandia National Laboratories · 2013

    Topic background · Storage technologies and grid services. The publisher notes that its historical cost and deployment figures are outdated.