Battery knowledge · Transport and modelling

Reduced-order model

A simplified version of a detailed model that keeps its dominant behaviour with far fewer states. The single-particle model is one reduction of the Newman model; others use polynomial profiles, Padé approximation or proper orthogonal decomposition. A ROM gives a BMS internal quantities, such as lithium concentration in the electrodes, that an equivalent circuit model cannot.

Abbreviation
ROM
Also called
model order reduction

Example

Transport and modelling: an example situation

The same concentration difference across 10 μm gives ten times the gradient across 100 μm; at equal D, first-law flux magnitude is ten times greater.

Read Reduced-order model alongside Battery management system in this context. The electronics and software that keep a battery inside its safe window: measuring every cell voltage and many temperatures, estimating SOC and SOH, balancing cells, computing current limits, controlling the contactors and reporting over the vehicle network.

Use in Lemonergy

Lemonergy Studio blocks

Observe an RC time constant

An RC circuit uses source, resistor, capacitor and reference blocks.

Blocks to use

  1. Controlled voltage source

    Applies voltage

    Inputs & settings
    • voltageV
  2. Resistor

    Sets resistance

    Inputs & settings
    • resistanceOhm
  3. Capacitor

    Stores charge

    Inputs & settings
    • capacitanceF
    • initialVoltageV
  4. Electrical reference

    Sets zero potential

    Inputs & settings
    • Connect p to reference net

This overview identifies the components to use. Follow the example in Lemonergy for their connections and settings.

  1. Keep R = 1 Ω and C = 1 F.
  2. Inspect capacitor voltage after one and two time constants.

Example. From zero initial voltage with a 1 V step, ideal capacitor voltage is about 0.632 V at 1 s and 0.865 V at 2 s.

Observe. Doubling resistance or capacitance doubles the time constant.

This generic circuit does not identify cell parameters from measurements.

Open the RC example →

References & further reading

Further reading on this topic

These sources provide broader context; they are not presented as citations for every statement in this entry.

  1. Modeling of Galvanostatic Charge and Discharge of the Lithium/Polymer/Insertion Cell

    Marc Doyle, Thomas F. Fuller, John Newman · Journal of The Electrochemical Society · 1993

    Topic background · Porous-electrode transport and insertion-cell modeling; foundational work rather than a specification for a particular commercial cell.

  2. Quantities, Units and Symbols in Physical Chemistry, 3rd edition, 2nd printing

    IUPAC · 2011

    Topic background · Physical-chemistry notation, thermodynamics, electrochemistry and transport quantities.