Battery knowledge · Lithium-ion chemistries and cell formats

Layered oxide

The crystal structure of LCO, NMC and NCA: close-packed oxygen layers with lithium and transition-metal ions in alternate layers of octahedral sites, so lithium moves in two-dimensional sheets. The structure offers high capacity and voltage but can distort or mix cations when deeply delithiated. Sodium versions are labelled O3 or P2 by their stacking. [1]

Abbreviation
LTMO
Also called
layered transition-metal oxide, α-NaFeO₂ structure, O3 structure, P2 structure

Example

Lithium-ion chemistries and cell formats: an example situation

Two cylindrical cells can share dimensions yet differ in cathode, capacity and current limits.

Read Layered oxide alongside LCO in this context. The original lithium-ion positive material, LiCoO₂, still used in phones and laptops for its high volumetric energy density. Cobalt cost and limited thermal stability keep it out of vehicles.

Use in Lemonergy

Separate chemistry from form factor.

This is a reference concept. No executable Lemonergy block has been verified for this term.

References & further reading

Technical references

  1. A reflection on lithium-ion battery cathode chemistry

    Arumugam Manthiram · Nature Communications · 2020

    Technical reference · Layered oxides, spinels and polyanion cathodes; links between composition, structure and performance.