Battery knowledge · Cell components and electrode materials

Anode overhang

The margin, of the order of a millimetre, by which the negative electrode extends beyond the positive electrode at every edge, so lithium leaving the cathode edge always finds graphite to enter rather than plating. The overhang slowly soaks up and gives back lithium itself, which causes small apparent capacity drifts in storage and efficiency tests.

Also called
negative electrode overhang, overhang effect

Example

Cell components and electrode materials: an example situation

Electrons travel through additive, foil and tab; ions use electrolyte and separator pathways.

Read Anode overhang alongside Calendar aging in this context. Degradation that happens with time even when a cell is not cycled — in storage, for example. It is driven mainly by side reactions such as SEI growth and accelerates with temperature.

Use in Lemonergy

Connect each material with its function.

This is a reference concept. No executable Lemonergy block has been verified for this term.

References & further reading

Further reading on this topic

These sources provide broader context; they are not presented as citations for every statement in this entry.

  1. DOE Explains… Batteries

    U.S. Department of Energy

    Topic background · Introductory account of electrodes, electrolyte and conversion between chemical and electrical energy.

  2. Current and future lithium-ion battery manufacturing

    Yangtao Liu, Ruihan Zhang, Jun Wang, Yan Wang · iScience · 2021

    Topic background · Electrode preparation, cell assembly, formation and manufacturing trade-offs.