Battery knowledge · State estimation

Weakest cell

The cell in a series string that reaches a voltage limit first — through lower capacity, higher resistance or a different SOC — and so sets the usable capacity and power of the whole pack. Balancing can correct an SOC offset but not a capacity deficit, so one weak cell among hundreds retires the pack early unless replaced.

Also called
limiting cell, weakest link

Example

The limiting cell matters

Average: 3.93 V. Highest cell: 4.02 V. The highest cell can reach the charge limit first.

The 4.2 V ceiling is an example, not universal. Voltage alone does not uniquely determine SOC.

Explore the graph

A pack average can hide a cell that reaches its voltage limit first.

Four cells before balancing
Four cells before balancingCell number versus Cell voltage (V). Individual voltages; Average; Example ceiling. Interpretation follows the graphs.3.713.851.7542.54.153.254.34Cell numberCell voltage (V)
Individual voltagesAverage (dashed)Example ceiling

Average: 3.93 V. Highest cell: 4.02 V. The highest cell can reach the charge limit first.

V_max = max(V₁, V₂, …); V_average = ΣV_i / N

Illustrative model. The 4.2 V ceiling is an example, not universal. Voltage alone does not uniquely determine SOC.

Use in Lemonergy

Distinguish internal states from noisy measurement estimates.

This is a reference concept. No executable Lemonergy block has been verified for this term.

References & further reading

Further reading on this topic

These sources provide broader context; they are not presented as citations for every statement in this entry.

  1. Extended Kalman filtering for battery management systems of LiPB-based HEV battery packs: Part 3. State and parameter estimation

    Gregory L. Plett · Journal of Power Sources · 2004

    Topic background · Model-based battery state-of-charge and parameter estimation with extended Kalman filtering, including uncertainty and model dependence.

  2. Extended Kalman filtering for battery management systems of LiPB-based HEV battery packs: Part 2. Modeling and identification

    Gregory L. Plett · Journal of Power Sources · 2004

    Topic background · Battery charge balance, open-circuit voltage, ohmic loss, polarization dynamics and model identification; parameters require cell-specific data.