Pre-lithiation

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First-cycle loss

The lithium consumed in forming the SEI on the first charge, which never returns to the positive electrode: about 5–10 % of capacity for graphite and far more for silicon. Pre-lithiation is the way to pay this debt in advance.

Formation

The first controlled charge and discharge cycles of a newly assembled cell, during which the SEI forms. It is part of cell production, before aging and grading.

Solid–electrolyte interphase

A film of electrolyte reaction products on the negative-electrode particles — graphite, and also silicon or lithium metal. It protects the electrode from further reaction but grows slowly for the whole life of the cell, consuming cyclable lithium.

Silicon anode

A negative electrode that uses silicon, which alloys with lithium and stores roughly ten times more charge per gram than graphite but swells by up to 300 %. Today it is blended into graphite at a few percent to limit the swelling.

References & further reading

Further reading on this topic

These sources provide broader context; they are not presented as citations for every statement in this entry.

1. Current and future lithium-ion battery manufacturing

   Yangtao Liu, Ruihan Zhang, Jun Wang, Yan Wang · iScience · 2021

   Topic background · Electrode preparation, cell assembly, formation and manufacturing trade-offs.