Anode active material

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Active material

The part of an electrode that actually stores lithium — graphite on the negative side, an oxide or phosphate on the positive. It makes up most of the electrode coating; the rest is binder and conductive additive.

Graphite

Layered carbon, the negative active material of nearly all lithium-ion cells. Lithium intercalates between its layers up to LiC₆, a theoretical 372 mAh/g, at a potential about 0.1 V above lithium metal.

Hard carbon

A disordered, non-graphitisable carbon used as the negative electrode of sodium-ion cells, where graphite barely works, and as a fast-charge additive in lithium-ion. Its open structure accepts ions without the strict layer spacing of graphite.

Lithium titanate

A negative active material, Li₄Ti₅O₁₂, that works at about 1.55 V above lithium, so it never plates lithium and forms almost no SEI. The price is a low cell voltage of about 2.4 V and low energy density, traded for very long life and fast charging.

Silicon anode

A negative electrode that uses silicon, which alloys with lithium and stores roughly ten times more charge per gram than graphite but swells by up to 300 %. Today it is blended into graphite at a few percent to limit the swelling.

References & further reading

Further reading on this topic

These sources provide broader context; they are not presented as citations for every statement in this entry.

1. DOE Explains… Batteries

   U.S. Department of Energy

   Topic background · Introductory account of electrodes, electrolyte and conversion between chemical and electrical energy.

2. Current and future lithium-ion battery manufacturing

   Yangtao Liu, Ruihan Zhang, Jun Wang, Yan Wang · iScience · 2021

   Topic background · Electrode preparation, cell assembly, formation and manufacturing trade-offs.