Battery knowledge · Cell components and electrode materials
Porous electrode
An electrode made of active-material particles, conductive additive and binder with electrolyte-filled pores between them. Its large internal surface is where the reaction happens. [1]
Example
Porosity reduces effective transport
At 40% porosity, D_eff is 25.298% of bulk diffusivity.
An empirical pore-structure assumption; actual tortuosity must be characterized.
Explore the graph
A Bruggeman relation approximates transport through a porous medium.
At 40% porosity, D_eff is 25.298% of bulk diffusivity.
D_eff = D εᵇ
Illustrative model. An empirical pore-structure assumption; actual tortuosity must be characterized.
Use in Lemonergy
Connect each material with its function.
This is a reference concept. No executable Lemonergy block has been verified for this term.
References & further reading
Technical references
- Modeling of Galvanostatic Charge and Discharge of the Lithium/Polymer/Insertion Cell
Marc Doyle, Thomas F. Fuller, John Newman · Journal of The Electrochemical Society · 1993
Technical reference · Porous-electrode transport and insertion-cell modeling; foundational work rather than a specification for a particular commercial cell.
Further reading on this topic
These sources provide broader context; they are not presented as citations for every statement in this entry.
- DOE Explains… Batteries
U.S. Department of Energy
Topic background · Introductory account of electrodes, electrolyte and conversion between chemical and electrical energy.
- Current and future lithium-ion battery manufacturing
Yangtao Liu, Ruihan Zhang, Jun Wang, Yan Wang · iScience · 2021
Topic background · Electrode preparation, cell assembly, formation and manufacturing trade-offs.