Sodium vanadium phosphate

Example

Use in Lemonergy

Do not carry lithium-ion assumptions into every chemistry.

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Connected concepts

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Hard carbon

A disordered, non-graphitisable carbon used as the negative electrode of sodium-ion cells, where graphite barely works, and as a fast-charge additive in lithium-ion. Its open structure accepts ions without the strict layer spacing of graphite.

Sodium iron pyrophosphate-phosphate

A polyanionic sodium-ion positive electrode, Na₄Fe₃(PO₄)₂P₂O₇, made from cheap iron and phosphate. With a hard-carbon negative it gives cells of about 2.8–3.0 V nominal with long cycle life and good thermal stability, but less energy than layered oxides. It plays the role LFP plays among lithium-ion chemistries.

Polyanionic cathode

A positive material built from transition metals and polyanion groups such as PO₄³⁻, SO₄²⁻ or P₂O₇⁴⁻. The strongly bonded groups raise the voltage through the inductive effect and hold oxygen tightly, giving long life and safety at some cost in capacity and conductivity. LFP is the lithium example; Na₃V₂(PO₄)₂F₃ and iron-based Na₄Fe₃(PO₄)₂P₂O₇ serve sodium-ion cells.

Power cell and energy cell

Two design points of the same chemistry: a power cell has thin, porous electrodes and many tabs for high current and fast charging; an energy cell has thick, dense electrodes for maximum watt-hours. A hybrid car wants the first, a long-range car the second.

Sodium-ion battery

A cell built like a lithium-ion cell but shuttling sodium ions, usually between a hard-carbon negative and a layered-oxide (NFM), polyanionic (NFPP, NVP) or Prussian-blue positive. It uses no lithium or cobalt and needs no copper foil, so it can be stored at 0 V, at the cost of lower energy density.

References & further reading

Further reading on this topic

These sources provide broader context; they are not presented as citations for every statement in this entry.

1. Promise and reality of post-lithium-ion batteries with high energy densities

   Jang Wook Choi, Doron Aurbach · Nature Reviews Materials · 2016

   Topic background · Post-lithium-ion materials and battery concepts, including practical cell-level limitations; historical 2016 perspective.

2. DOE/EPRI 2013 Electricity Storage Handbook in Collaboration with NRECA

   Sandia National Laboratories · 2013

   Topic background · Storage technologies and grid services. The publisher notes that its historical cost and deployment figures are outdated.