Hydrometallurgy

Example

Use in Lemonergy

Distinguish recovered material from a qualified product.

This is a reference concept. No executable Lemonergy block has been verified for this term.

Connected concepts

Related concepts from the knowledge graph. Connections show context, not cause and effect. Hover or focus a linked term for its definition.

Black mass

The dark powder of mixed electrode materials left after end-of-life cells are discharged, shredded and separated from their casings, foils and separators. It is the traded intermediate that hydrometallurgical refiners buy.

Direct recycling

Recovering cathode material with its crystal structure intact and relithiating it for reuse, instead of breaking it down to metal salts. It promises lower energy and cost but must handle a mix of chemistries and ages.

Leaching

Dissolving the metals in black mass, usually in sulfuric acid with hydrogen peroxide as a reducing agent so cobalt and manganese go into solution as their more soluble lower oxidation state. The leach liquor carries lithium, nickel, cobalt and manganese, plus impurities such as copper and aluminium.

Pyrometallurgy

Recycling by smelting whole cells or modules in a furnace, which recovers nickel, cobalt and copper as an alloy but loses lithium, aluminium and graphite to the slag. It is robust to mixed feed and is often the first step before a hydrometallurgical finish.

Battery recycling

Recovering lithium, nickel, cobalt, copper and aluminium from end-of-life cells and production scrap. Scrap is today’s main feedstock; vehicle returns will dominate in the 2030s, and regulation now sets minimum recovery rates.

Solvent extraction

Separating metals in the leach liquor by contacting it with an organic phase carrying an extractant that picks up one metal at a time, controlled by pH: manganese, then cobalt, then nickel, leaving lithium in the water. It is how recyclers reach battery-grade sulfates.

References & further reading

Technical references

1. Recycling lithium-ion batteries from electric vehicles

   Gavin Harper et al. · Nature · 2019

   Technical reference · Reuse, disassembly and mechanical, hydro-, pyro- and direct recycling routes.

Further reading on this topic

These sources provide broader context; they are not presented as citations for every statement in this entry.

2. Lithium-Ion Battery Recycling

   U.S. Environmental Protection Agency

   Topic background · Battery construction, recycling routes and U.S. waste-management context.