Battery knowledge · Electrochemistry fundamentals

Electric double layer

The thin region at an electrode surface where ions in the electrolyte line up against the charge on the electrode, behaving like a capacitor. It stores a little charge without any reaction and shapes the high-frequency part of an impedance spectrum.

Example

Capacitor charge and energy

At 5 V: 25 C and 62.5 J.

Ideal constant capacitance; leakage, series resistance and voltage rating excluded.

Explore the graph

Charge rises linearly with voltage; energy rises with voltage squared.

Stored charge
Stored chargeVoltage (V) versus Charge (C). Q = CV. Interpretation follows the graphs.006.251.2512.52.518.83.75255Voltage (V)Charge (C)
Q = CV
Stored energy
Stored energyVoltage (V) versus Energy (J). E = ½CV². Interpretation follows the graphs.0015.61.2531.32.546.93.7562.55Voltage (V)Energy (J)
E = ½CV²

At 5 V: 25 C and 62.5 J.

Q = CV; E = ½CV²

Illustrative model. Ideal constant capacitance; leakage, series resistance and voltage rating excluded.

Use in Lemonergy

Connect reaction sites and transport paths.

This is a reference concept. No executable Lemonergy block has been verified for this term.

References & further reading

Further reading on this topic

These sources provide broader context; they are not presented as citations for every statement in this entry.

  1. Quantities, Units and Symbols in Physical Chemistry, 3rd edition, 2nd printing

    IUPAC · 2011

    Topic background · Physical-chemistry notation, thermodynamics, electrochemistry and transport quantities.