{
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    "label": "Working and counter electrode",
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      "name": "Working and counter electrode",
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        "working electrode",
        "counter electrode",
        "auxiliary electrode"
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      "section": "topic-testing",
      "definition": "The two current-carrying electrodes of an electrochemical test: the working electrode is the one being studied, and the counter electrode completes the circuit. In a lithium half-cell the lithium counter electrode doubles as the reference; adding a separate reference electrode makes a three-electrode cell that isolates the working electrode.",
      "related": [
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        "reference-electrode",
        "half-cell",
        "potentiostat"
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      "url": "https://lemonergy.com/learn/glossary/working-and-counter-electrode/",
      "mentions": [
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      "id": "topic:topic-testing",
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        "id": "topic-testing",
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        "lede": "The measurements and test procedures that characterise a cell or pack, from capacity and pulse tests to abuse and environmental tests.",
        "context": "Record specimen, state, instrument, temperature and timing.",
        "example": "Resistance immediately after a current step can differ from a ten-second value because slower polarization contributes.",
        "lesson_url": "https://lemonergy.com/learn/fundamentals/capacity-and-c-rate/",
        "lesson_label": "Open capacity measurements"
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        "definition": "A full cell with an added reference electrode, so the potential of each working electrode can be tracked separately during cycling. It reveals, for instance, when the graphite potential drops below 0 V and plating begins.",
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        "section": "topic-testing",
        "definition": "An electrode of stable, known potential against which another is measured. In lithium-ion work it is a piece of lithium metal, which defines the Li/Li⁺ scale; outside it the standard hydrogen electrode is the primary reference.",
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        "definition": "A test cell with the electrode under study against lithium metal, so the measured potential is that electrode’s alone. It is how a new material’s capacity and voltage are first measured, usually in coin-cell format.",
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      "id": "term:potentiostat",
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        "id": "potentiostat",
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        "section": "topic-testing",
        "definition": "An instrument that controls the potential of an electrode against a reference and measures the current, or the reverse as a galvanostat. It is the tool for electrochemical impedance spectroscopy and three-electrode experiments.",
        "related": [
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      "id": "term:electrode",
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      "properties": {
        "id": "electrode",
        "name": "Electrode",
        "section": "topic-components",
        "definition": "A solid conductor where the cell’s reaction happens, in contact with the electrolyte. A lithium-ion cell has a negative electrode and a positive electrode, each a porous coating on a metal foil.",
        "related": [
          "negative-electrode",
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          "porous-electrode",
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        "lesson": "fundamentals/cell-anatomy/#components",
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          "title": "Two transport paths",
          "text": "Electrons need connected solid paths to the collector; ions need electrolyte paths to reaction sites. More of one constituent displaces others at fixed volume."
        },
        "url": "https://lemonergy.com/learn/glossary/electrode/",
        "mentions": [
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}
