{
  "node": {
    "id": "term:lifsi",
    "type": "Term",
    "label": "Lithium bis(fluorosulfonyl)imide",
    "properties": {
      "id": "lifsi",
      "name": "Lithium bis(fluorosulfonyl)imide",
      "abbr": "LiFSI",
      "section": "topic-electrolytes",
      "definition": "A salt with higher conductivity and far better thermal and moisture stability than LiPF₆, increasingly blended with it or used in fast-charge and lithium-metal electrolytes. Its drawback is corrosion of aluminium at high voltage unless LiPF₆ is also present.",
      "related": [
        "lipf6",
        "lithium-salt",
        "litfsi",
        "fast-charging"
      ],
      "url": "https://lemonergy.com/learn/glossary/lifsi/",
      "mentions": []
    }
  },
  "edges": [
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      "source": "term:lifsi",
      "target": "topic:topic-electrolytes",
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        "sourceFile": "terms.json"
      }
    },
    {
      "id": "edge:3418",
      "source": "term:lifsi",
      "target": "term:lipf6",
      "type": "relatedTo",
      "properties": {
        "sourceFile": "terms.json",
        "meaning": "Related context; not a causal claim"
      }
    },
    {
      "id": "edge:3419",
      "source": "term:lifsi",
      "target": "term:lithium-salt",
      "type": "relatedTo",
      "properties": {
        "sourceFile": "terms.json",
        "meaning": "Related context; not a causal claim"
      }
    },
    {
      "id": "edge:3420",
      "source": "term:lifsi",
      "target": "term:litfsi",
      "type": "relatedTo",
      "properties": {
        "sourceFile": "terms.json",
        "meaning": "Related context; not a causal claim"
      }
    },
    {
      "id": "edge:3421",
      "source": "term:lifsi",
      "target": "term:fast-charging",
      "type": "relatedTo",
      "properties": {
        "sourceFile": "terms.json",
        "meaning": "Related context; not a causal claim"
      }
    },
    {
      "id": "edge:3422",
      "source": "term:lifsi",
      "target": "reference:xu-electrolytes",
      "type": "cites",
      "properties": {
        "sourceFile": "wiki-references.json",
        "scope": "direct technical reference"
      }
    }
  ],
  "neighbors": [
    {
      "id": "topic:topic-electrolytes",
      "type": "Topic",
      "label": "Electrolytes and separators",
      "properties": {
        "id": "topic-electrolytes",
        "name": "Electrolytes and separators",
        "lede": "What sits between the electrodes: liquid, gel and solid electrolytes, their salts, solvents and additives, and the separator that keeps the electrodes apart.",
        "context": "Connect transport with electronic isolation.",
        "example": "Greater liquid uptake may improve wetting while changing mechanical behavior. Several properties define separator performance.",
        "lesson_url": "https://lemonergy.com/learn/fundamentals/cell-anatomy/",
        "lesson_label": "Open cell anatomy"
      }
    },
    {
      "id": "term:lipf6",
      "type": "Term",
      "label": "Lithium hexafluorophosphate",
      "properties": {
        "id": "lipf6",
        "name": "Lithium hexafluorophosphate",
        "abbr": "LiPF₆",
        "section": "topic-electrolytes",
        "definition": "The lithium salt in nearly every commercial electrolyte, chosen for conductivity, aluminium passivation and cost rather than stability: it decomposes above about 60 °C and reacts with water to form HF.",
        "related": [
          "lithium-salt",
          "hydrofluoric-acid",
          "lifsi",
          "dry-room",
          "aluminium-foil"
        ],
        "url": "https://lemonergy.com/learn/glossary/lipf6/",
        "mentions": [
          "electrolyte",
          "passivation"
        ]
      }
    },
    {
      "id": "term:lithium-salt",
      "type": "Term",
      "label": "Lithium salt",
      "properties": {
        "id": "lithium-salt",
        "name": "Lithium salt",
        "aka": [
          "LiPF₆",
          "LiFSI"
        ],
        "section": "topic-electrolytes",
        "definition": "The dissolved salt that supplies the mobile lithium ions in a liquid electrolyte, almost always lithium hexafluorophosphate, LiPF₆, at about one mole per litre. It reacts with traces of water to form hydrofluoric acid, which is why cells are filled in a dry room.",
        "related": [
          "electrolyte",
          "carbonate-solvent",
          "dry-room",
          "hydrofluoric-acid"
        ],
        "url": "https://lemonergy.com/learn/glossary/lithium-salt/",
        "mentions": [
          "lipf6"
        ]
      }
    },
    {
      "id": "term:litfsi",
      "type": "Term",
      "label": "Lithium bis(trifluoromethanesulfonyl)imide",
      "properties": {
        "id": "litfsi",
        "name": "Lithium bis(trifluoromethanesulfonyl)imide",
        "abbr": "LiTFSI",
        "section": "topic-electrolytes",
        "definition": "A very stable imide salt used in polymer and solid-state electrolytes and in research cells. Like LiFSI it attacks aluminium current collectors above about 3.7 V, which keeps it out of mainstream liquid cells.",
        "related": [
          "lifsi",
          "lipf6",
          "polymer-electrolyte",
          "lithium-salt"
        ],
        "url": "https://lemonergy.com/learn/glossary/litfsi/",
        "mentions": []
      }
    },
    {
      "id": "term:fast-charging",
      "type": "Term",
      "label": "Fast charging",
      "properties": {
        "id": "fast-charging",
        "name": "Fast charging",
        "section": "topic-charging",
        "definition": "Charging intended to replenish a specified amount of energy or state of charge in a short time. There is no universal C-rate threshold: performance depends on cell chemistry, temperature, starting state and power limits. High current can increase heating and lithium-plating risk, requiring appropriate limits.",
        "related": [
          "lithium-plating",
          "c-rate",
          "cc-cv-charging",
          "dc-fast-charging",
          "thermal-management",
          "mscc"
        ],
        "url": "https://lemonergy.com/learn/glossary/fast-charging/",
        "mentions": [
          "state-of-charge"
        ]
      }
    },
    {
      "id": "reference:xu-electrolytes",
      "type": "Reference",
      "label": "Electrolytes and Interphases in Li-Ion Batteries and Beyond",
      "properties": {
        "title": "Electrolytes and Interphases in Li-Ion Batteries and Beyond",
        "publisher": "Chemical Reviews",
        "url": "https://doi.org/10.1021/cr500003w",
        "type": "Review article",
        "scope": "Electrolyte salts, solvents, additives and electrode interphases.",
        "year": 2014,
        "authors": [
          "Kang Xu"
        ],
        "accessed": "2026-10-27"
      }
    }
  ]
}
