{
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      "id": "catholyte",
      "name": "Catholyte",
      "section": "topic-electrolytes",
      "definition": "In a solid-state cell, the solid electrolyte mixed into the positive electrode so ions can reach every particle, as liquid does in a conventional cell. It can be a different material from the separator layer.",
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        "solid-electrolyte",
        "halide-electrolyte",
        "sulfide-electrolyte",
        "porous-electrode"
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      "label": "Electrolytes and separators",
      "properties": {
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        "name": "Electrolytes and separators",
        "lede": "What sits between the electrodes: liquid, gel and solid electrolytes, their salts, solvents and additives, and the separator that keeps the electrodes apart.",
        "context": "Connect transport with electronic isolation.",
        "example": "Greater liquid uptake may improve wetting while changing mechanical behavior. Several properties define separator performance.",
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        "lesson_label": "Open cell anatomy"
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        "definition": "A solid ion conductor that replaces the liquid electrolyte in an all-solid-state cell. Oxide, sulfide, halide and polymer families each need a different production route.",
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      "id": "term:halide-electrolyte",
      "type": "Term",
      "label": "Halide electrolyte",
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        "id": "halide-electrolyte",
        "name": "Halide electrolyte",
        "aka": [
          "Li₃YCl₆",
          "Li₃InCl₆"
        ],
        "section": "topic-electrolytes",
        "definition": "A newer solid electrolyte family of lithium metal chlorides and bromides, stable at the high voltage of layered oxide cathodes where sulfides decompose, but unstable against lithium metal. Cells often pair a halide catholyte with a sulfide separator.",
        "related": [
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        "mentions": [
          "separator",
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      "id": "term:sulfide-electrolyte",
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      "label": "Sulfide electrolyte",
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        "name": "Sulfide electrolyte",
        "aka": [
          "LPSCl",
          "argyrodite",
          "LGPS"
        ],
        "section": "topic-electrolytes",
        "definition": "The solid electrolyte family with the highest conductivity — argyrodites such as Li₆PS₅Cl match liquids, and LGPS exceeds them — and soft enough to be pressed rather than sintered. Their weakness is reaction with moisture, which releases hydrogen sulfide.",
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        "mentions": [
          "electrolyte"
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      "id": "term:porous-electrode",
      "type": "Term",
      "label": "Porous electrode",
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        "name": "Porous electrode",
        "section": "topic-components",
        "definition": "An electrode made of active-material particles, conductive additive and binder with electrolyte-filled pores between them. Its large internal surface is where the reaction happens.",
        "related": [
          "porosity",
          "tortuosity",
          "active-material",
          "porous-electrode-theory",
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        "url": "https://lemonergy.com/learn/glossary/porous-electrode/",
        "mentions": [
          "electrode",
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          "conductive-additive"
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      "id": "term:electrode",
      "type": "Term",
      "label": "Electrode",
      "properties": {
        "id": "electrode",
        "name": "Electrode",
        "section": "topic-components",
        "definition": "A solid conductor where the cell’s reaction happens, in contact with the electrolyte. A lithium-ion cell has a negative electrode and a positive electrode, each a porous coating on a metal foil.",
        "related": [
          "negative-electrode",
          "positive-electrode",
          "porous-electrode",
          "current-collector"
        ],
        "lesson": "fundamentals/cell-anatomy/#components",
        "example": {
          "title": "Two transport paths",
          "text": "Electrons need connected solid paths to the collector; ions need electrolyte paths to reaction sites. More of one constituent displaces others at fixed volume."
        },
        "url": "https://lemonergy.com/learn/glossary/electrode/",
        "mentions": [
          "electrolyte",
          "coating"
        ]
      }
    },
    {
      "id": "term:positive-electrode",
      "type": "Term",
      "label": "Positive electrode",
      "properties": {
        "id": "positive-electrode",
        "name": "Positive electrode",
        "section": "topic-components",
        "definition": "The electrode at the higher potential: a lithium metal oxide or phosphate coated on aluminium foil. It is the lithium source when a cell is built, and industry calls it the cathode.",
        "related": [
          "cathode",
          "cathode-active-material",
          "negative-electrode",
          "aluminium-foil"
        ],
        "lesson": "fundamentals/cell-anatomy/#anode-cathode",
        "example": {
          "title": "Polarity and reaction",
          "text": "The positive electrode retains its polarity label while its electrochemical reaction reverses between charge and discharge."
        },
        "url": "https://lemonergy.com/learn/glossary/positive-electrode/",
        "mentions": [
          "electrode"
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    {
      "id": "term:separator",
      "type": "Term",
      "label": "Separator",
      "properties": {
        "id": "separator",
        "name": "Separator",
        "section": "topic-electrolytes",
        "definition": "A porous, electronically insulating film between the electrodes. Electrons cannot cross it; ions move through the electrolyte in its pores.",
        "related": [
          "electrolyte",
          "ceramic-coated-separator",
          "separator-shutdown",
          "internal-short-circuit",
          "porosity"
        ],
        "lesson": "fundamentals/cell-architecture/#separator",
        "example": {
          "title": "Different conduction paths",
          "text": "A separator prevents direct electronic contact while permitting ionic transport through its electrolyte-filled structure."
        },
        "url": "https://lemonergy.com/learn/glossary/separator/",
        "mentions": []
      }
    },
    {
      "id": "term:electrolyte",
      "type": "Term",
      "label": "Electrolyte",
      "properties": {
        "id": "electrolyte",
        "name": "Electrolyte",
        "section": "topic-electrolytes",
        "definition": "The ion-conducting medium between the electrodes. In a liquid-electrolyte cell it fills the pores of both electrodes and the separator, so it is not a separate structural layer.",
        "related": [
          "lithium-salt",
          "carbonate-solvent",
          "electrolyte-additive",
          "ionic-conductivity",
          "solid-electrolyte",
          "ionic-liquid-electrolyte"
        ],
        "lesson": "fundamentals/cell-architecture/#electrolyte",
        "example": {
          "title": "Ions and electrons",
          "text": "Electrolyte carries ions between electrodes; the external circuit carries electrons. The two paths serve different roles."
        },
        "url": "https://lemonergy.com/learn/glossary/electrolyte/",
        "mentions": [
          "separator"
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      }
    }
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}
