{
  "node": {
    "id": "term:anode-free",
    "type": "Term",
    "label": "Anode-free cell",
    "properties": {
      "id": "anode-free",
      "name": "Anode-free cell",
      "aka": [
        "zero-excess lithium"
      ],
      "section": "topic-other-chemistries",
      "definition": "A lithium-metal cell assembled with bare copper foil as the negative electrode; the first charge plates all its lithium out of the positive material. It maximises energy density but every lost lithium atom is lost capacity.",
      "related": [
        "lithium-metal-battery",
        "lithium-plating",
        "coulombic-efficiency"
      ],
      "url": "https://lemonergy.com/learn/glossary/anode-free/",
      "mentions": [
        "electrode",
        "negative-electrode",
        "copper-foil",
        "energy-density"
      ]
    }
  },
  "edges": [
    {
      "id": "edge:748",
      "source": "term:anode-free",
      "target": "topic:topic-other-chemistries",
      "type": "belongsTo",
      "properties": {
        "sourceFile": "terms.json"
      }
    },
    {
      "id": "edge:749",
      "source": "term:anode-free",
      "target": "term:lithium-metal-battery",
      "type": "relatedTo",
      "properties": {
        "sourceFile": "terms.json",
        "meaning": "Related context; not a causal claim"
      }
    },
    {
      "id": "edge:750",
      "source": "term:anode-free",
      "target": "term:lithium-plating",
      "type": "relatedTo",
      "properties": {
        "sourceFile": "terms.json",
        "meaning": "Related context; not a causal claim"
      }
    },
    {
      "id": "edge:751",
      "source": "term:anode-free",
      "target": "term:coulombic-efficiency",
      "type": "relatedTo",
      "properties": {
        "sourceFile": "terms.json",
        "meaning": "Related context; not a causal claim"
      }
    },
    {
      "id": "edge:mentions/anode-free/electrode",
      "source": "term:anode-free",
      "target": "term:electrode",
      "type": "mentions",
      "properties": {
        "sourceFile": "terms.json",
        "method": "build_glossary.mention_index + mentions",
        "field": "definition",
        "meaning": "Text mention; not a causal claim"
      }
    },
    {
      "id": "edge:mentions/anode-free/negative-electrode",
      "source": "term:anode-free",
      "target": "term:negative-electrode",
      "type": "mentions",
      "properties": {
        "sourceFile": "terms.json",
        "method": "build_glossary.mention_index + mentions",
        "field": "definition",
        "meaning": "Text mention; not a causal claim"
      }
    },
    {
      "id": "edge:mentions/anode-free/copper-foil",
      "source": "term:anode-free",
      "target": "term:copper-foil",
      "type": "mentions",
      "properties": {
        "sourceFile": "terms.json",
        "method": "build_glossary.mention_index + mentions",
        "field": "definition",
        "meaning": "Text mention; not a causal claim"
      }
    },
    {
      "id": "edge:mentions/anode-free/energy-density",
      "source": "term:anode-free",
      "target": "term:energy-density",
      "type": "mentions",
      "properties": {
        "sourceFile": "terms.json",
        "method": "build_glossary.mention_index + mentions",
        "field": "definition",
        "meaning": "Text mention; not a causal claim"
      }
    }
  ],
  "neighbors": [
    {
      "id": "topic:topic-other-chemistries",
      "type": "Topic",
      "label": "Other and emerging chemistries",
      "properties": {
        "id": "topic-other-chemistries",
        "name": "Other and emerging chemistries",
        "lede": "Batteries beyond today’s lithium-ion: lead, nickel and primary cells, flow and metal–air batteries, solid-state and lithium-metal cells, and the multivalent and sodium chemistries in development.",
        "context": "Do not carry lithium-ion assumptions into every chemistry.",
        "example": "Two chemistries can meet the same energy target with different voltage windows and charge termination.",
        "lesson_url": "https://lemonergy.com/learn/fundamentals/cell-anatomy/",
        "lesson_label": "Open cell anatomy"
      }
    },
    {
      "id": "term:lithium-metal-battery",
      "type": "Term",
      "label": "Lithium-metal battery",
      "properties": {
        "id": "lithium-metal-battery",
        "name": "Lithium-metal battery",
        "section": "topic-other-chemistries",
        "definition": "A rechargeable cell whose negative electrode is lithium metal rather than a host material. It promises much higher energy density than lithium-ion, but lithium deposits unevenly on charge, so dendrites and short life have kept it from the mass market.",
        "related": [
          "lithium-metal-anode",
          "dendrite",
          "solid-state-battery",
          "anode-free"
        ],
        "url": "https://lemonergy.com/learn/glossary/lithium-metal-battery/",
        "mentions": [
          "electrode",
          "negative-electrode",
          "energy-density"
        ]
      }
    },
    {
      "id": "term:lithium-plating",
      "type": "Term",
      "label": "Lithium plating",
      "properties": {
        "id": "lithium-plating",
        "name": "Lithium plating",
        "section": "topic-aging",
        "definition": "Lithium metal depositing on the negative-electrode surface instead of intercalating into it. It is promoted by charging at low temperature or high current.",
        "related": [
          "dendrite",
          "fast-charging",
          "intercalation",
          "np-ratio",
          "dead-lithium",
          "electrodeposition"
        ],
        "lesson": "fundamentals/battery-aging/#plating",
        "url": "https://lemonergy.com/learn/glossary/lithium-plating/",
        "mentions": []
      }
    },
    {
      "id": "term:coulombic-efficiency",
      "type": "Term",
      "label": "Coulombic efficiency",
      "properties": {
        "id": "coulombic-efficiency",
        "name": "Coulombic efficiency",
        "abbr": "CE",
        "section": "topic-ratings",
        "definition": "Charge delivered on discharge divided by charge put in on the previous charge. A healthy lithium-ion cell exceeds 99.9 %; the missing fraction is lithium lost to side reactions, so CE is an early and sensitive aging signal.",
        "formula": "CE = Q_discharge / Q_charge",
        "unit": "%",
        "related": [
          "energy-efficiency",
          "loss-of-lithium-inventory",
          "sei",
          "formation"
        ],
        "example": {
          "title": "Compare charge in and charge out",
          "text": "If a defined test charges 5.00 Ah and subsequently discharges 4.95 Ah over the chosen voltage window, its coulombic efficiency is 99%. This ratio alone does not include voltage-related energy loss."
        },
        "url": "https://lemonergy.com/learn/glossary/coulombic-efficiency/",
        "mentions": []
      }
    },
    {
      "id": "term:electrode",
      "type": "Term",
      "label": "Electrode",
      "properties": {
        "id": "electrode",
        "name": "Electrode",
        "section": "topic-components",
        "definition": "A solid conductor where the cell’s reaction happens, in contact with the electrolyte. A lithium-ion cell has a negative electrode and a positive electrode, each a porous coating on a metal foil.",
        "related": [
          "negative-electrode",
          "positive-electrode",
          "porous-electrode",
          "current-collector"
        ],
        "lesson": "fundamentals/cell-anatomy/#components",
        "example": {
          "title": "Two transport paths",
          "text": "Electrons need connected solid paths to the collector; ions need electrolyte paths to reaction sites. More of one constituent displaces others at fixed volume."
        },
        "url": "https://lemonergy.com/learn/glossary/electrode/",
        "mentions": [
          "electrolyte",
          "coating"
        ]
      }
    },
    {
      "id": "term:negative-electrode",
      "type": "Term",
      "label": "Negative electrode",
      "properties": {
        "id": "negative-electrode",
        "name": "Negative electrode",
        "section": "topic-components",
        "definition": "The electrode at the lower potential, usually graphite on copper foil in a lithium-ion cell. It holds the lithium when the cell is charged and releases it on discharge, and industry calls it the anode.",
        "related": [
          "anode",
          "graphite",
          "positive-electrode",
          "copper-foil"
        ],
        "lesson": "fundamentals/cell-anatomy/#anode-cathode",
        "example": {
          "title": "Keep the polarity name",
          "text": "Graphite remains the negative electrode during charge and discharge, while the anode/cathode reaction labels change with operating direction."
        },
        "url": "https://lemonergy.com/learn/glossary/negative-electrode/",
        "mentions": [
          "electrode"
        ]
      }
    },
    {
      "id": "term:copper-foil",
      "type": "Term",
      "label": "Copper foil",
      "properties": {
        "id": "copper-foil",
        "name": "Copper foil",
        "section": "topic-components",
        "definition": "The negative current collector, typically 6–10 µm thick. Copper is used because it is stable at the low potential of a graphite electrode, where aluminium would alloy with lithium.",
        "related": [
          "current-collector",
          "aluminium-foil",
          "over-discharge",
          "copper-dissolution"
        ],
        "example": {
          "title": "Count collector mass",
          "text": "At equal area and density, doubling foil thickness doubles foil mass. Active-material-only capacity omits that mass change."
        },
        "url": "https://lemonergy.com/learn/glossary/copper-foil/",
        "mentions": [
          "electrode",
          "graphite"
        ]
      }
    },
    {
      "id": "term:energy-density",
      "type": "Term",
      "label": "Energy density",
      "properties": {
        "id": "energy-density",
        "name": "Energy density",
        "aka": [
          "volumetric energy density"
        ],
        "section": "topic-ratings",
        "definition": "Stored energy per unit volume, in watt-hours per litre. It is the figure that matters when space is the constraint, as in a phone or under a car floor; high-energy cylindrical cells pass 700 Wh/L.",
        "unit": "Wh/L",
        "related": [
          "specific-energy",
          "nominal-energy",
          "ragone-plot",
          "areal-loading"
        ],
        "lesson": "fundamentals/capacity-and-c-rate/#energy",
        "url": "https://lemonergy.com/learn/glossary/energy-density/",
        "mentions": []
      }
    }
  ]
}