{
  "node": {
    "id": "term:alloying",
    "type": "Term",
    "label": "Alloying reaction",
    "properties": {
      "id": "alloying",
      "name": "Alloying reaction",
      "section": "topic-electrochemistry",
      "definition": "An electrode mechanism in which lithium forms an alloy with the host, as it does with silicon, tin or aluminium. It stores far more lithium per atom than intercalation at the cost of volume changes of several hundred percent.",
      "related": [
        "silicon-anode",
        "intercalation",
        "conversion-reaction",
        "particle-cracking",
        "tin-anode"
      ],
      "url": "https://lemonergy.com/learn/glossary/alloying/",
      "mentions": [
        "electrode"
      ]
    }
  },
  "edges": [
    {
      "id": "edge:1986",
      "source": "term:alloying",
      "target": "topic:topic-electrochemistry",
      "type": "belongsTo",
      "properties": {
        "sourceFile": "terms.json"
      }
    },
    {
      "id": "edge:1987",
      "source": "term:alloying",
      "target": "term:silicon-anode",
      "type": "relatedTo",
      "properties": {
        "sourceFile": "terms.json",
        "meaning": "Related context; not a causal claim"
      }
    },
    {
      "id": "edge:1988",
      "source": "term:alloying",
      "target": "term:intercalation",
      "type": "relatedTo",
      "properties": {
        "sourceFile": "terms.json",
        "meaning": "Related context; not a causal claim"
      }
    },
    {
      "id": "edge:1989",
      "source": "term:alloying",
      "target": "term:conversion-reaction",
      "type": "relatedTo",
      "properties": {
        "sourceFile": "terms.json",
        "meaning": "Related context; not a causal claim"
      }
    },
    {
      "id": "edge:1990",
      "source": "term:alloying",
      "target": "term:particle-cracking",
      "type": "relatedTo",
      "properties": {
        "sourceFile": "terms.json",
        "meaning": "Related context; not a causal claim"
      }
    },
    {
      "id": "edge:1991",
      "source": "term:alloying",
      "target": "term:tin-anode",
      "type": "relatedTo",
      "properties": {
        "sourceFile": "terms.json",
        "meaning": "Related context; not a causal claim"
      }
    },
    {
      "id": "edge:mentions/alloying/electrode",
      "source": "term:alloying",
      "target": "term:electrode",
      "type": "mentions",
      "properties": {
        "sourceFile": "terms.json",
        "method": "build_glossary.mention_index + mentions",
        "field": "definition",
        "meaning": "Text mention; not a causal claim"
      }
    }
  ],
  "neighbors": [
    {
      "id": "topic:topic-electrochemistry",
      "type": "Topic",
      "label": "Electrochemistry fundamentals",
      "properties": {
        "id": "topic-electrochemistry",
        "name": "Electrochemistry fundamentals",
        "lede": "The reactions and potentials that make a cell a battery.",
        "context": "Connect reaction sites and transport paths.",
        "example": "A circuit can predict terminal voltage while leaving electrode potentials and reaction kinetics unresolved.",
        "lesson_url": "https://lemonergy.com/learn/fundamentals/cell-anatomy/",
        "lesson_label": "Open cell anatomy"
      }
    },
    {
      "id": "term:silicon-anode",
      "type": "Term",
      "label": "Silicon anode",
      "properties": {
        "id": "silicon-anode",
        "name": "Silicon anode",
        "aka": [
          "silicon-graphite",
          "SiOx"
        ],
        "section": "topic-components",
        "definition": "A negative electrode that uses silicon, which alloys with lithium and stores roughly ten times more charge per gram than graphite but swells by up to 300 %. Today it is blended into graphite at a few percent to limit the swelling.",
        "related": [
          "graphite",
          "alloying",
          "particle-cracking",
          "swelling",
          "self-healing-binder"
        ],
        "example": {
          "title": "Read the mixture basis",
          "text": "A silicon-containing electrode may be a blend rather than pure silicon. A silicon percentage needs a clear mass basis."
        },
        "url": "https://lemonergy.com/learn/glossary/silicon-anode/",
        "mentions": [
          "electrode",
          "negative-electrode"
        ]
      }
    },
    {
      "id": "term:intercalation",
      "type": "Term",
      "label": "Intercalation",
      "properties": {
        "id": "intercalation",
        "name": "Intercalation",
        "section": "topic-electrochemistry",
        "definition": "Lithium inserting into, and leaving, the host structure of an electrode material — between graphite layers, for example — without destroying it.",
        "related": [
          "graphite",
          "rocking-chair",
          "lithium-plating",
          "conversion-reaction",
          "alloying"
        ],
        "lesson": "fundamentals/battery-aging/#plating",
        "url": "https://lemonergy.com/learn/glossary/intercalation/",
        "mentions": [
          "electrode"
        ]
      }
    },
    {
      "id": "term:conversion-reaction",
      "type": "Term",
      "label": "Conversion reaction",
      "properties": {
        "id": "conversion-reaction",
        "name": "Conversion reaction",
        "section": "topic-electrochemistry",
        "definition": "An electrode reaction in which the host compound is broken down and reformed, as sulfur or a metal fluoride is, rather than lithium slotting into an intact structure. Conversion materials store more charge than intercalation hosts but suffer large volume change and voltage hysteresis.",
        "related": [
          "intercalation",
          "alloying",
          "lithium-sulfur",
          "voltage-hysteresis"
        ],
        "url": "https://lemonergy.com/learn/glossary/conversion-reaction/",
        "mentions": [
          "electrode"
        ]
      }
    },
    {
      "id": "term:particle-cracking",
      "type": "Term",
      "label": "Particle cracking",
      "properties": {
        "id": "particle-cracking",
        "name": "Particle cracking",
        "section": "topic-aging",
        "definition": "Fracture of active-material particles from the volume change of repeated lithium insertion and removal. New surfaces consume electrolyte to form fresh SEI, and fragments that lose contact no longer store lithium.",
        "related": [
          "cycle-aging",
          "loss-of-active-material",
          "silicon-anode",
          "single-crystal",
          "depth-of-discharge"
        ],
        "lesson": "fundamentals/battery-aging/#cracking",
        "url": "https://lemonergy.com/learn/glossary/particle-cracking/",
        "mentions": [
          "electrolyte",
          "sei"
        ]
      }
    },
    {
      "id": "term:tin-anode",
      "type": "Term",
      "label": "Tin anode",
      "properties": {
        "id": "tin-anode",
        "name": "Tin anode",
        "aka": [
          "Sn anode",
          "tin-based anode",
          "Sn–Co–C"
        ],
        "section": "topic-components",
        "definition": "A negative electrode using tin, which alloys with lithium up to about Li₄.₄Sn for a theoretical 994 mAh/g, nearly three times graphite. Its volume grows by roughly 260 % on lithiation, so tin is used in composites; Sony’s 2005 Nexelion cell had an amorphous tin–cobalt–carbon anode. Tin also alloys with sodium, making it a sodium-ion candidate.",
        "related": [
          "alloying",
          "silicon-anode",
          "anode-active-material",
          "sodium-ion",
          "particle-cracking"
        ],
        "url": "https://lemonergy.com/learn/glossary/tin-anode/",
        "mentions": [
          "milliampere-hour",
          "electrode",
          "negative-electrode",
          "anode",
          "graphite",
          "calcination",
          "cobalt"
        ]
      }
    },
    {
      "id": "term:electrode",
      "type": "Term",
      "label": "Electrode",
      "properties": {
        "id": "electrode",
        "name": "Electrode",
        "section": "topic-components",
        "definition": "A solid conductor where the cell’s reaction happens, in contact with the electrolyte. A lithium-ion cell has a negative electrode and a positive electrode, each a porous coating on a metal foil.",
        "related": [
          "negative-electrode",
          "positive-electrode",
          "porous-electrode",
          "current-collector"
        ],
        "lesson": "fundamentals/cell-anatomy/#components",
        "example": {
          "title": "Two transport paths",
          "text": "Electrons need connected solid paths to the collector; ions need electrolyte paths to reaction sites. More of one constituent displaces others at fixed volume."
        },
        "url": "https://lemonergy.com/learn/glossary/electrode/",
        "mentions": [
          "electrolyte",
          "coating"
        ]
      }
    }
  ]
}